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Alt 19.10.2003, 16:33   #5   Druckbare Version zeigen
buba Männlich
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Re: Sicherheitsdatenblatt gesucht

Zitat:
Originalnachricht erstellt von Last of the Sane
Ich suche ein Sicherheitsdatenblatt für Triethylphosphit (122-52-1). Bei Sigma-Aldrich scheints das zu geben. Aber ich komm nicht ran, die Registrierung funktioniert irgendwie nicht.
Code:
Valid 05/2003 - 07/2003

Sigma-Aldrich Chemie GmbH
Riedstrasse 2
D-89555 Steinheim
Deutschland
Tel: 07329/970
Nacht: 07329/310



             M A T E R I A L  S A F E T Y  D A T A  S H E E T
             
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
    CATALOG #:            T61204
    NAME:                 TRIETHYL PHOSPHITE, 98%
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
    CAS #:   122-52-1
    MF: C6H15O3P
    EC NO:  204-552-5
  ADDITIONAL INFORMATION
    CONTAINS DIETHYL PHOSPHITE, CHEMICAL ABSTRACTS REGISTRY
    NUMBER 762-04-9.
    CONTAINS TRIETHYL PHOSPHATE, CHEMICAL ABSTRACTS REGISTRY
    NUMBER 78-40-0.
  SYNONYMS
    FOSFORYN TROJETYLOWY (CZECH) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
  LABEL PRECAUTIONARY STATEMENTS
    FLAMMABLE
    HARMFUL
    FLAMMABLE.
    HARMFUL IF SWALLOWED.
    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
    TARGET ORGAN(S):
    NERVES
    LIVER
    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
    WATER AND SEEK MEDICAL ADVICE.
    WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
    CALL A PHYSICIAN.
    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
    IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER
    FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND
    SHOES. CALL A PHYSICIAN.
    IN CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER
    FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING
    THE EYELIDS WITH FINGERS. CALL A PHYSICIAN.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
  EXTINGUISHING MEDIA
    WATER SPRAY.
    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
  SPECIAL FIREFIGHTING PROCEDURES
    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
    PREVENT CONTACT WITH SKIN AND EYES.
  UNUSUAL FIRE AND EXPLOSIONS HAZARDS
    FLAMMABLE LIQUID.
    EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
    FLASH BACK.
    CONTAINER EXPLOSION CAN OCCUR UNDER FIRE CONDITIONS. IN ADVANCED OR
    MASSIVE FIRES THE AREA SHOULD BE EVACUATED AND THE FIRE SHOULD BE
    FOUGHT FROM A REMOTE EXPLOSION-RESISTANT LOCATION.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
    RUBBER GLOVES.
    COVER WITH DRY-LIME, SAND, OR SODA ASH. PLACE IN COVERED CONTAINERS
    USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.
    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
    EVACUATE AREA.
    SHUT OFF ALL SOURCES OF IGNITION.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
    REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
    SAFETY SHOWER AND EYE BATH.
    USE NONSPARKING TOOLS.
    MECHANICAL EXHAUST REQUIRED.
    DO NOT BREATHE VAPOR.
    AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
    AVOID PROLONGED OR REPEATED EXPOSURE.
    NIOSH/MSHA-APPROVED RESPIRATOR.
    COMPATIBLE CHEMICAL-RESISTANT GLOVES.
    CHEMICAL SAFETY GOGGLES.
    KEEP CONTAINER CLOSED.
    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
    STORE IN A COOL DRY PLACE.
    WASH THOROUGHLY AFTER HANDLING.
    WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
  PHYSICAL PROPERTIES
    BOILING POINT:        153 - 157  C
    FLASHPOINT               130F
                             54.44C
    SPECIFIC GRAVITY:     0.955
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
  STABILITY
    STABLE.
  CONDITIONS TO AVOID
    MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR WATER.
  INCOMPATIBILITIES
    STRONG OXIDIZING AGENTS
    STRONG BASES
  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
    CARBON MONOXIDE, CARBON DIOXIDE
    THERMAL DECOMPOSITION MAY PRODUCE TOXIC FUMES OF PHOSPHORUS OXIDES
    AND/OR PHOSPHINE.
  HAZARDOUS POLYMERIZATION
    WILL NOT OCCUR.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
  ACUTE EFFECTS
    CAUSES SKIN IRRITATION.
    MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
    CAUSES EYE IRRITATION.
    MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
    RESPIRATORY TRACT.
    MAY BE HARMFUL IF INHALED.
    HARMFUL IF SWALLOWED.
    CHEMICAL PNEUMONITIS.
  CHRONIC EFFECTS
    TARGET ORGAN(S):
    NERVES
    LIVER, KIDNEYS
    BLADDER
  RTECS #: TH1130000
    PHOSPHOROUS ACID, TRIETHYL ESTER
  IRRITATION DATA
    SKN-RBT 500 MG MLD                            ATDAEI 1,218,1992
    EYE-RBT 100 MG MOD                            ATDAEI 1,218,1992
    SKN-MAM 500 MG MLD                            MEPAAX 29,393,1978
    EYE-MAM 100 MG MLD                            MEPAAX 29,393,1978
  TOXICITY DATA
    ORL-RAT LD50:1840 MG/KG                       ATDAEI 1,218,1992
    IHL-RAT LC50:11063 MG/M3/6H                   ATDAEI 1,218,1992
    ORL-MUS LD50:3720 MG/KG                       ATDAEI 1,218,1992
    IHL-MUS LC50:6203 MG/M3/6H                    ATDAEI 1,218,1992
    SKN-RBT LD50:2800 MG/KG                       ATDAEI 1,218,1992
  TARGET ORGAN DATA
    BEHAVIORAL (ATAXIA)
    LUNGS, THORAX OR RESPIRATION (RESPIRATORY STIMULATION)
    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
    COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
    DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
    CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF
    THIS MATERIAL.
    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND
    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
    FLAMMABLE.
    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
    CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
  EUROPEAN INFORMATION
    FLAMMABLE
    HARMFUL
    R 10
    FLAMMABLE.
    R 22
    HARMFUL IF SWALLOWED.
    R 36/37/38
    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
    S 16
    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
    S 26
    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
    WATER AND SEEK MEDICAL ADVICE.
    S 36
    WEAR SUITABLE PROTECTIVE CLOTHING.
  REVIEWS, STANDARDS, AND REGULATIONS
    OEL=MAK
    NOHS 1974: HZD 84307; NIS 3; TNF 38; NOS 18; TNE 5414
    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
    COPYRIGHT 2001 SIGMA-ALDRICH CO.
    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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